Pyrometallurgy Innovation Centre (PYROSEARCH)

  • High-temperature experimental and thermodynamic modelling research on the pyrometallurgical processing of copper

    Hidayat, Taufiq; Shishin, Denis; Decterov, Sergei A.; Hayes, Peter C.; Jak, Evgueni (2017). Uncertainty in the metal price and competition between producers mean that the daily operation of a smelter needs to target high recovery of valuable elements at low operating cost. Options for the improvement of the plant operation can be examined and decision making can be informed based on accurate information from laboratory experimentation coupled with predictions using advanced thermodynamic models. Integrated high-temperature experimental and thermodynamic modelling research on phase equilibria and thermodynamics of copper-containing systems have been undertaken at the Pyrometallurgy Innovation Centre (PYROSEARCH). The experimental phase equilibria studies involve high-temperature equilibration, rapid quenching and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA). The thermodynamic modelling deals with the development of accurate thermodynamic database built through critical evaluation of experimental data, selection of solution models, and optimization of models parameters. The database covers the Al-Ca-Cu-Fe-Mg-O-S-Si chemical system. The gas, slag, matte, liquid and solid metal phases, spinel solid solution as well as numerous solid oxide and sulphide phases are included. The database works within the FactSage software environment. Examples of phase equilibria data and thermodynamic models of selected systems, as well as possible implementation of the research outcomes to selected copper making processes are presented.

  • The synergistic copper process - a new process route for low-energy copper production

    Hawker, William; Vaughan, James; Jak, Evgueni; Hayes, Peter C. (2016). A new process concept has been developed that will enable significant increases in productivity to be achieved from existing copper smelting and converting operations. Key to the Synergistic Copper Process is the utilisation of the excess enthalpy currently available from the sulphide oxidation reactions that take place pyrometallurgical processing. The process involves the preparation of precipitated oxide forms of copper and their introduction of this intermediate product into copper smelting and converting reactors. The precipitated oxide can be prepared using any leaching technology to recover copper ions in aqueous solution. The solution is treated to increase the pH of the solution and produce selective precipitation of firstly iron and then copper. The intermediate copper product can be then be pre-treated utilising low grade waste heat to remove residual free or chemically-bound water before being introduced directly into the pyrometallurgical reactors as a supplemental copper feed source. The process can be used in conjunction with all presently-used pyrometallurgical copper production process technologies. This process route provides an attractive alternative to the SX/EW route currently employed industrially to recover copper from oxidised and some sulphide ores. The process can be adapted to any virtually method of obtaining leach copper. The precipitated intermediate product has grades comparable with conventional sulphide concentrates and can be blended with other copper smelter feedstocks or used directly as a high-copper, low-iron feedstock in the smelting or converting stages. The process enables smelter productivity to be increased with minimal capital expenditure on smelter upgrades; provides an alternative method of preparation and of utilising new copper-containing intermediate products to improve overall copper recovery.

  • Selected phase equilibria studies in the Al2O3-CaO-SiO2 system

    Haccuria, Elien; Crivits, Tijl; Hayes, Peter C.; Jak, Evgueni (2016).

  • Solubility of MgO in high Cu2O slags in equilibrium with Cu metal

    Crivits, T.; Hayes, P. C.; Jak, E. (2016).

  • Integrated experimental and modelling research on copper-making slags

    Hidayat, T.; Shishin, D.; Decterov, S.; Hayes, P. C.; Jak, E. (2016).